Free practice questions

Leaving Cert Chemistry — Example Quiz

Twenty free Leaving Cert Chemistry practice questions on atomic structure, bonding, moles, reaction rates and organic chemistry, with explanations.

20 questions chemistryleaving-certsciencesecond-level

Example study questions — not affiliated with, endorsed by, or derived from any examining body's exam papers or question banks.

  1. 1

    An atom of an element has 11 protons, 12 neutrons and 11 electrons. What is its mass number?

    • A 11
    • B 23
    • C 22
    • D 34
    Show answer

    Answer: B

    Mass number is protons plus neutrons: 11 + 12 = 23. Electrons are not counted, as their mass is negligible. The atomic number is 11, which identifies the element as sodium.

  2. 2

    Which type of bonding occurs between a metal and a non-metal?

    • A Covalent
    • B Metallic
    • C Ionic
    • D Hydrogen
    Show answer

    Answer: C

    A metal loses electrons to form a positive ion and a non-metal gains them to form a negative ion; the resulting electrostatic attraction is an ionic bond. Covalent bonding involves shared electrons between non-metals, and metallic bonding occurs between metal atoms.

  3. 3 Select all that apply

    Which TWO of the following are properties typical of ionic compounds? (Select two.)

    • A Low melting point
    • B Conduct electricity when molten
    • C Generally soluble in water
    • D Conduct electricity when solid
    Show answer

    Answer: B, C

    Ionic compounds conduct only when the ions are free to move — molten or in solution, not in the solid lattice. They are generally water-soluble and have high melting points because of the strong electrostatic forces throughout the lattice.

  4. 4

    How many moles are present in 36 g of water? (Relative molecular mass of H₂O = 18)

    • A 0.5 mol
    • B 1 mol
    • C 2 mol
    • D 18 mol
    Show answer

    Answer: C

    Moles = mass ÷ relative molecular mass = 36 ÷ 18 = 2 mol. Each mole of water contains 6.02 × 10²³ molecules, so this sample contains roughly 1.2 × 10²⁴ molecules.

  5. 5

    Going down a group in the periodic table, atomic radius increases.

    • A True
    • B False
    Show answer

    Answer: A

    True. Each successive element down a group has an additional occupied energy level, so the outer electrons sit further from the nucleus. Increased shielding by inner electrons also reduces the effective nuclear pull on them.

  6. 6

    A solution has a pH of 3. It is best described as:

    • A Weakly basic
    • B Acidic
    • C Neutral
    • D Strongly basic
    Show answer

    Answer: B

    pH below 7 is acidic, and 3 is strongly so. The scale is logarithmic, so pH 3 has ten times the hydrogen ion concentration of pH 4 and a hundred times that of pH 5.

  7. 7 Select all that apply

    Which THREE of the following will increase the rate of a chemical reaction? (Select three.)

    • A Increasing the temperature
    • B Decreasing the surface area of a solid reactant
    • C Adding a catalyst
    • D Increasing the concentration of a reactant
    Show answer

    Answer: A, C, D

    Higher temperature gives particles more kinetic energy, so collisions are more frequent and more of them exceed the activation energy. A catalyst lowers activation energy. Higher concentration means more frequent collisions. Decreasing surface area slows a reaction down — increasing it speeds it up.

  8. 8

    What is the general formula of an alkane?

    • A CₙH₂ₙ
    • B CₙH₂ₙ₋₂
    • C CₙHₙ
    • D CₙH₂ₙ₊₂
    Show answer

    Answer: D

    Alkanes are saturated hydrocarbons with the formula CₙH₂ₙ₊₂ — methane is CH₄, ethane C₂H₆. CₙH₂ₙ is the alkene general formula, and CₙH₂ₙ₋₂ is that of the alkynes.

  9. 9

    Which particle determines the identity of an element?

    • A Neutron
    • B Proton
    • C Electron
    • D Positron
    Show answer

    Answer: B

    The number of protons is the atomic number, and it defines the element. Changing the neutron count gives an isotope of the same element; changing the electron count gives an ion of the same element. Change the proton count and it is a different element entirely.

  10. 10 Put these in order

    Place the following steps of a volumetric analysis (titration) in the correct order.

    • A Fill the burette with the solution of known concentration
    • B Record the burette reading at the end point
    • C Rinse the pipette with the solution it will contain
    • D Add indicator to the conical flask and titrate
    Show answer

    Correct order

    1. C Rinse the pipette with the solution it will contain
    2. A Fill the burette with the solution of known concentration
    3. D Add indicator to the conical flask and titrate
    4. B Record the burette reading at the end point

    Apparatus is rinsed with the solution it will hold, so residual water cannot dilute it. The burette is then filled with the standard solution. Indicator is added to the measured aliquot in the conical flask, the titration is carried out, and the reading at the end point is recorded.

  11. 11

    What is the oxidation number of hydrogen in most of its compounds?

    • A +1
    • B −1
    • C 0
    • D +2
    Show answer

    Answer: A

    Hydrogen is +1 in most compounds. The exception is in metal hydrides such as sodium hydride (NaH), where the more electronegative hydrogen takes −1. Uncombined H₂ has an oxidation number of 0.

  12. 12

    A catalyst increases the yield of product in a reversible reaction at equilibrium.

    • A True
    • B False
    Show answer

    Answer: B

    False. A catalyst speeds up the forward and reverse reactions equally, so equilibrium is reached sooner but its position is unchanged — the yield is the same. Only changes in concentration, pressure or temperature shift the position of equilibrium.

  13. 13

    Which of the following is an example of an exothermic process?

    • A Melting ice
    • B Photosynthesis
    • C Combustion of methane
    • D Thermal decomposition of limestone
    Show answer

    Answer: C

    Combustion releases heat to the surroundings, so it is exothermic. Melting, photosynthesis and thermal decomposition all absorb energy and are endothermic.

  14. 14

    Isotopes of the same element differ in their number of:

    • A Protons
    • B Neutrons
    • C Electrons
    • D Protons and electrons
    Show answer

    Answer: B

    Isotopes have the same atomic number but different mass numbers, which means the same protons and a different number of neutrons. Chlorine-35 and chlorine-37 both have 17 protons; they differ by two neutrons.

  15. 15

    Which gas is produced when a dilute acid reacts with a metal carbonate?

    • A Hydrogen
    • B Oxygen
    • C Chlorine
    • D Carbon dioxide
    Show answer

    Answer: D

    Acid plus carbonate gives a salt, water and carbon dioxide, which turns limewater milky. Hydrogen is the gas produced when a dilute acid reacts with a reactive metal, which is the distinction being tested here.

  16. 16 Select all that apply

    Which TWO of the following are noble gases? (Select two.)

    • A Argon
    • B Chlorine
    • C Nitrogen
    • D Neon
    Show answer

    Answer: A, D

    Argon and neon are in group 0 (group 18), with full outer energy levels, which is why they are so unreactive. Chlorine is a halogen in group 7, and nitrogen is in group 5.

  17. 17

    In the electrolysis of molten sodium chloride, which product forms at the cathode?

    • A Chlorine gas
    • B Sodium metal
    • C Hydrogen gas
    • D Oxygen gas
    Show answer

    Answer: B

    The cathode is negative, so it attracts positive ions. Sodium ions are reduced there by gaining an electron to form sodium metal. Chloride ions are oxidised at the anode to give chlorine gas.

  18. 18

    The relative atomic mass of chlorine is 35.5 because naturally occurring chlorine is a mixture of isotopes.

    • A True
    • B False
    Show answer

    Answer: A

    True. Chlorine occurs as roughly 75% chlorine-35 and 25% chlorine-37. The relative atomic mass is the weighted average of the isotopic masses, which lands at about 35.5 — no individual chlorine atom has that mass.

  19. 19

    Which functional group characterises an alcohol?

    • A −COOH
    • B −CHO
    • C −OH
    • D −NH₂
    Show answer

    Answer: C

    The hydroxyl group −OH defines an alcohol, as in ethanol (C₂H₅OH). −COOH is a carboxylic acid, −CHO an aldehyde, and −NH₂ an amine.

  20. 20

    What colour does litmus turn in a basic solution?

    • A Red
    • B Blue
    • C Green
    • D Colourless
    Show answer

    Answer: B

    Litmus is red in acid and blue in base. A useful memory aid is that both "base" and "blue" begin with B. Universal indicator gives a fuller range, running through green at neutral to purple in strong base.


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